Read e-book online An Introduction to Thermal Physics PDF

By Daniel V. Schroeder

ISBN-10: 0201380277

ISBN-13: 9780201380279

This article seems to be at thermodynamics and statistical mechanics. half I introduces thoughts of thermodynamics and statistical mechanics from a unified view. components II and III discover extra purposes of classical thermodynamics and statistical mechanics. all through, the emphasis is on real-world functions.

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18. Heat conduction across the dotted line occurs because the molecules moving from box 1 to box 2 have a different average energy than the molecules moving from box 2 to box 1. For free motion between these boxes, each should have a width of roughly one mean free path. 1 x­ * For that matter, I haven't even given a definition of what constitutes a collision. After all, even when molecules pass at a distance, they attract and deflect each other somewhat. For a more careful treatment of transport processes in gases, see Reif (1965).

Consider the combustion of one mole of methane gas: CH4(gas) + 202(gas) ,-> C02 (gas) + 2H20(gas). The system is at standard temperature (298 K) and pressure (10 5 Pa) both before and after the reaction. First imagine the process of converting a mole of methane into its elemental consituents (graphite and hydrogen gas). Use the data at the back of this book to find tlH for this process. Now imagine forming a mole of C02 and two moles of water vapor from their elemental constituents. Determine tlH for this process.

I : I, . , I : .. ' I I' . • I I . ,' . . 'I I : . . ··1 I • I, . ~ '. ' . 18. Heat conduction across the dotted line occurs because the molecules moving from box 1 to box 2 have a different average energy than the molecules moving from box 2 to box 1. For free motion between these boxes, each should have a width of roughly one mean free path. 1 x­ * For that matter, I haven't even given a definition of what constitutes a collision. After all, even when molecules pass at a distance, they attract and deflect each other somewhat.

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An Introduction to Thermal Physics by Daniel V. Schroeder


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